Fourier transform emission spectroscopy and ab initio calculations on the visible spectrum of AlD

Wojciech Szajna,Rafał Hakalla,Keith Moore,Ian C. Lane

Journal of Quantitative Spectroscopy and Radiative Transfer（2018）

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摘要

•High resolution analysis of AlD+ (A2Π - X2Σ+) FTS spectra.•Improved molecular constants of the X2Σ+ state of AlD+.•Experimental and theoretical study of the Λ-doubling of the A2Π v=0,1 levels.•Spin-orbit potentials to the first two atomic limits.•Calculated lifetimes and branching ratios for the A2Π and B2Σ+ states of AlD+.

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关键词

AlD+ Isotopologue,Visible spectrum,FT Spectroscopy,Molecular parameters,Λ−Doubling,Ab initio calculations,Spin-orbit coupling,Excited state lifetimes,Laser cooling

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