The Asymmetric Construction of CF3-containing Spiro-Thiazolone-pyrrolidine Compounds Via [3 + 2] Cycloaddition.

Boyu Li,Jikun Liu,Fengyun Gao,Mengmeng Sun,Yifei Guo,Yuan Zhou,Dongwa Wen,Yabo Deng,Hui Chen,Kairong Wang,Wenjin Yan

Organic & biomolecular chemistry（2019）

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摘要

The first organocatalytic method for the asymmetric construction of CF3-containing spiro-thiazolone-pyrrolidine compounds has been developed. This is one of the very few methods to reach spiro-thiazolones, and afforded the products in excellent yields and stereoselectivities catalysed by only 1 mol% cinchona alkaloid-derived catalyst.

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