Negative activation volume of oxygen self-diffusion in forsterite

Physics of the Earth and Planetary Interiors(2018)

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摘要
•Oxygen self-diffusion in forsterite has a negative activation volume.•Ionic conduction in forsterite is controlled by O diffusion at pressures >10 GPa.•The conductivity profile in the deep asthenosphere is explained by O diffusion.
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关键词
Oxygen self-diffusion,Pressure dependence,Activation volume,Forsterite,Ionic conductivity,Upper mantle
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