Conversion of ethylene into propylene with the siliceous SSZ-13 zeolite prepared without an organic structure-directing agent

Journal of Catalysis(2018)

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摘要
•Siliceous (silica/alumina ratio > 20) SSZ-13 zeolite was obtained without organics.•Because of high SAR, as-synthesized SSZ-13 can be steamed at high temperature.•Steaming increased SAR and porosity, and removed octahedral aluminum effectively.•The SSZ-13s showed remarkable catalyses in ethylene conversion into propylene.•The remarkable catalyses were due to adequate SAR and removal of strong acid sites.
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关键词
Dealumination,Ethylene-to-propylene conversion,SSZ-13,Steaming,Structure-directing agent-free,Zeolite synthesis
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