Modification of acidic and textural properties of a sulphated zirconia catalyst for efficient conversion of high-density polyethylene into liquid fuel

Consumption of plastic has a rapid increase of about 8% per annum and reached to 400 million per tonnes approximately, where about 50% of plastic was disposed after using only once. Different techniques for treating this increased waste faced a number of issues related to cost and environmental and sustainable development. Catalytic conversion has been found as one of the most viable solution s to solve this problem. Sulphated zirconia (SZ) catalyst modified with calcium carbide (CC) was found to improve high - density polyethylene ( HDPE ) conversion into liquid fuel. The liquid content was improved from 39.0wt% to 66.0wt% at 410 °C. HDPE was converted 100% by weight using, SZ/CC with 66wt% liquid yield as compared to the conversion of approximately 98wt% with about 40wt% only liquid yield for the pure SZ. The composition of hydrocarbon liquid product was significantly changed from paraffin (16%) and aromatic (58%) to olefin (74%) and naphthenic (23%) compounds. This significant increase in liquid was related to changes in the acidic and textural characteristics of the new hybrid catalyst, SZ/CC where the total ammonia desorption of 337.0 μm NH 3 /g for the SZ was modified to 23.4 μm NH 3 /g for the SZ/CC. Both SZ and SZ/CC catalysts showed characteristics of mesoporous material, where the internal pore volume of SZ had reduced from 0.21 mL/g for SZ to 0.04 mL/g for SZ/CC. Furthermore, XRD analysis indicated the presence of a new compound, CaZrO 3 in the SZ/CC, which confirmed a chemical interaction between the SZ and CC through sintering of ZrO 2 and CaO. Therefore, the SZ/CC catalyst improves the liquid yield significantly and the selectivity towards olefinic and naphthenic compounds.