Targetable Mechanical Properties by Switching between Self-Sorting and Co-assembly with Formed Tripodal Ketoenamine Supramolecular Hydrogels.
CHEMNANOMAT(2018)
摘要
A new family of supramolecular hydrogelators are introduced in which self-sorting and co-assembly can be utilised in the tuneability of the mechanical properties of the materials, a property closely tied to the nanostructure of the gel network. The insitu reactivity of the components of the gelators allows for system chemistry concepts to be applied to the formation of the gels and shows that molecular properties, and not necessarily the chemical identity, determines some gel properties in these family of gels.
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关键词
supramolecular gel,self-sorting,co-assembly,dynamic covalent chemistry,nanofibers
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