Augmented hydrogen production by gasification of ball milled polyethylene with Ca(OH) 2 and Ni(OH) 2

Polymer thermal recycling for hydrogen production is a promising process to recover such precious element from plastic waste. In the present work a simple but efficacious high energy milling pretreatment is proposed to boost H 2 generation during polyethylene gasification. The polymer is comilled with calcium and nickel hydroxides and then it is subjected to thermal treatment. Results demonstrate the key role played by the calcium hydroxide that significantly ameliorates hydrogen production. It reacts in solid state with the polyethylene to form directly carbonate and hydrogen. In this way, the CO 2 is immediately captured in solid form, thus shifting the equilibrium toward H 2 generation and obtaining high production rate (>25 L/mol CH 2 ). In addition, high amounts of the hydroxide prevent excessive methane formation, so the gas product is almost pure hydrogen (~95%).