Palladium–nickel Materials As Cathode Electrocatalysts for Alkaline Fuel Cells

In this work, Pd-Ni catalysts supported on carbon nanofibers were synthesized, with metal contents and Pd:Ni atomic ratios close to 25 wt.% and 1:2, respectively. Previously, the carbon nanofibers were chemically treated, in order to create surface oxygen and/or nitrogen groups. The synthesized catalysts displayed low crystallinity degree and high dispersion on carbon supports, especially in those with surface functional groups. Oxygen reduction reaction (ORR) was studied by rotating ring-disk electrode (RRDE) techniques. When the kinetic current is normalized by the mass of Pd present in the electrode, higher activities were obtained for the synthesized materials in comparison with the activity observed for a commercial Pd/C E-TEK catalyst. Some differences are reported for the different materials under study, mainly dependent on the presence of oxygen surface groups on the carbon support. In light of the results, we can propose the synthesized catalysts as possible candidates for cathodes in alkaline direct methanol fuel cells. (C) 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.