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Preparation of Aryne–Nickel Complexes from Ortho-Borylaryl Triflates

Yuto Sumida,Tomoe Sumida,Daisuke Hashizume,Takamitsu Hosoya

Organic letters（2016）

Cited 43|Views3
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Abstract
A facile method for preparing diverse aryne-nickel complexes from readily synthesized ortho-borylaryl triflates is described. Exploratory synthetic applications, including the synthesis of 1,2-difunctionalized arenes, based on the nucleophilic character of the aryne-nickel complexes are also demonstrated.
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