Asymmetric Synthesis of Chiral α‐Substituted Mercaptoglycine Derivatives via α‐Sulfenylation of Ni(II) Complex of Glycine and S‐Substituted 4‐Methylbenzenesulfonothioate

Jia Li,Xiaohan Song,Shengbin Zhou,Jiang Wang,Hong Liu

CHINESE JOURNAL OF CHEMISTRY（2017）

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摘要

The asymmetric alpha-sulfenylation of Ni(II) complex of glycine with S-substituted 4-methylbenzenesulfonothioate is reported. Due to the mild and simple reaction conditions, this asymmetric reaction is compatible with various functional groups.

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关键词

alpha-sulfenylation,asymmetric synthesis,Ni(II) complex,chiral alpha-substituted mercaptoglycine derivatives

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