Inhibition of ligand arm hydrolysis and carboxylate coordination directed formation of μ4-oxido-bridged [Cu4] complexes: Synthesis, X-ray structure and functional activity

Inorganica Chimica Acta(2019)

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摘要
Critical role of carboxylate bridging was examined for carboxylate coordination assisted aggregation in [Cu4(µ4–O)(µ–L1)2(µ1,3–O2CCH3)4]·H2O (2a) and [Cu4(µ4–O)(µ–L1)2(µ1,3–O2CC2H5)4]·H2O (2b) avoiding ligand imine arm hydrolysis.
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关键词
Tetracopper coordination aggregate,Schiff base,μ4-Oxido-bridge,Catechol oxidase,ct-DNA,HSA
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