Synthesis of Carbonate Esters by Carboxymethylation Using NaAlO2 as a Highly Active Heterogeneous Catalyst

Sreerangappa Ramesh,Kiran Indukuri,Olivier Riant,Damien P. Debecker

Organic Process Research & Development（2018）

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摘要

Sodium aluminate is presented as a highly active heterogeneous catalyst that is able to convert a range of alcohols into the corresponding unsymmetrical carbonate esters by reaction with dimethyl carbonate. Preparing NaAlO2 via spray drying boosts the basic properties and the activity of the catalyst.

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关键词

spray drying,sodium aluminate,dimethyl carbonate,mixed carbonate esters,carboxymethylation

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