Ligand Controlled Structure of Cadmium(ii) Metal-Organic Frameworks for Fluorescence Sensing of Fe3+ Ion and Nitroaromatic Compounds

Three cadmium(II) metal-organic frameworks (MOFs) based on tetracarboxylate ligands, namely [Cd-2(TTTA)(DMF)(3)]center dot 2DMF(1), [Cd-2(TB)(H2O)(4)]center dot 3DMF center dot H2O (2) and [Cd(TEB)(0.5)]center dot 2DMF center dot 4H(2)O (3) have been designed and synthesized. Complex 1 is a 2-dimensional (2D) 3,4-connected network with 3,4L13 topology, complex 2 features a 3-dimensional (3D) 3,4-connected tfa topology with a 2-fold interpenetrating structure and complex 3 has a 3D 4-connected dia topology with a 4-fold interpenetrating structure. Interestingly, 2 exhibits permanent pores and selective adsorption of CO2 over CH4. In addition, 2 shows fluorescence sensing of Fe3+ ion and rapid detection of nitroaromatic compounds (NACs) through fluorescence quenching. (C) 2018 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.