Lithium benzenechromiumtricarbonyl as C-nucleophile in the cross-dehydrogenative coupling reactions of azaaromatics

Alexey I. Nemytov,Irina A. Utepova,Oleg N. Chupakhin,Pavel A. Slepukhin,Valery N. Charushin

Inorganica Chimica Acta（2019）

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摘要

•Lithium benzenechromiumtricarbonyl has first been suggested as original C-nucleophile in the reaction with azines.•The series of previously unknown azinylbenzenechromiumtricarbonyls have been obtained.•Intermediates have been isolated and characterized.

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关键词

Lithium benzenechromiumtricarbonyl,Nucleophilic substitution of hydrogen,Heterocycles,CC coupling

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