Celite-Polyaniline supported palladium catalyst for chemoselective hydrogenation reactions: Celite-Polyaniline-Pd catalyzed chemoselective hydrogenation reactions
APPLIED ORGANOMETALLIC CHEMISTRY(2019)
摘要
Polyaniline coated on particles of celite is used as support to load palladium catalyst. This heterogenized Celite center dot PANI center dot Pd system, is used as an efficient catalyst for chemoselective hydrogenation reactions. The catalyst is characterized by usual spectral, analytical techniques and studied for hydrogenation reactions at ambient conditions. The mild reaction conditions allow the control over the reactions and excellent selectivity is achieved in number of conversions. Hydrogenation of a carbon-carbon double bond was favored over other polar pi-bond systems, while labile functional groups such as benzyl ether, benzyl esters, cyano, nitro and halogen remained unaffected. Primary amines were converted to N,N-dimethyl amines with formaldehyde, the double bond of coumarin was selectively hydrogenated without opening of the lactone functionality.
更多查看译文
关键词
celite center dot PANI support,chemoselective transformations,heterogeneous catalysis,hydrogenation,palladium catalysis
AI 理解论文
溯源树
样例
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要