Screening of single and binary catalysts for oxidative coupling of methane to value-added chemicals

Molecular Catalysis(2019)

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摘要
•The most active among the 91 tested binary catalyst was Na2WO4-Mn/SiO2.•The α-cristobalite phase and the Na2WO4:Mn ratio are critical for the activity.•The optimal C2+ yield was 23.54%, with 60.5% selectivity.•The stability of Na2WO4-Mn/SiO2 was good over 50 h of testing.•Catalyst sintering and phase transformation caused slow catalyst deactivation.
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关键词
Catalyst screening,Light hydrocarbons,Metal oxide catalyst,Oxidative coupling of methane,Silica support
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