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Phosphacycles As Building Blocks for Main Group Cages.

Angewandte Chemie(2013)

引用 17|浏览7
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摘要
Kationische Pniktogen/Kohlenstoff-Käfige werden in der Reaktion von 2,4,6-Tri-tert-butyl-1,3,5-triphosphabenzol mit den Carben-Mimetika EX2+ (E=P, As) gebildet. Mit E=P wird 1,4-Addition an die heteroaromatische Verbindung beobachtet, mit E=As entstehen Käfigkomplexe. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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关键词
arsenic,carbene mimics,phosphabenzene,phosphorus,X-ray diffraction
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