Quantitative speciation of insoluble chlorine in E-waste open burning soil: Implications of the presence of unidentified aromatic-Cl and insoluble chlorides

Open burning of electronic waste (E-waste) produces numerous organochlorine compounds (OCs). Although the presence of unidentified OCs has been suggested, the mass balance of identified and unidentified OCs in E-waste open burning soils (EOBSs) still remains unknown. In this study, the concentrations of Cl bonded with aromatic carbon (aromatic-Cl) and aliphatic carbon (aliphatic-Cl), and inorganic Cl in EOBSs were determined by focusing on chlorine (Cl) in water-insoluble fractions (insoluble Cl) and applying Cl K-edge X-ray absorption spectroscopy in conjunction with combustion ion chromatography. The concentrations of identified Cl (Cl in five individual OCs: polychlorinated biphenyls, polychlorinated dibenzo-p-dioxins, polychlorinated dibenzofurans, chlorinated polycyclic aromatic hydrocarbons and chlorinated benzenes) were calculated from the concentrations previously reported for the same samples. The proportions of identified Cl were less than 1% to aromatic-Cl, indicating the abundance of unidentified OCs. The concentrations of both aromatic-Cl and identified Cl were highest in the sample collected from the site in Vietnam (VN), where wires and cables were mainly burned, suggesting that unidentified aromatic-Cl were produced through pathways similar to those of identified OCs, and the pathway could be related to burning of wires and cables. Further, insoluble Cu (II) compound, Cu2(OH)3Cl were assumed to be present in EOBSs and the concentration was highest in VN, implying that insoluble inorganic chlorides could be related to the formation of aromatic-Cl and identified Cl.