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Total Synthesis of Hoiamide A Using an Evans–Tishchenko Reaction As a Key Step

Yian Guo,Jingjing Zhou,Bowen Gao,Meng Zhao,Jia-Lei Yan,Zhengshuang Xu,Sun Choi,Tao Ye

Organic letters（2019）

Cited 13|Views6
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Abstract
The first total synthesis of neurotoxic cyclodepsipeptide hoiamide A (1) has been accomplished. The synthesis features the use of an Evans-Tishchenko fragment coupling between a five-stereogenic-center-containing β-hydroxyketone and a chiral aldehyde derived from threonine.
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