Unusually Strong Heteroatomic Bonding In The Complex Polyanion Of Intermetallic Ba6pt22al53

The new intermetallic compound Ba6Pt22Al53 was obtained from reaction of the elements. The title compound crystallizes in the hexagonal crystal system with lattice parameters of a = 1427.5(3) and c = 1614.3(4) pm and space group P6(3)/mcm (Z = 2) and adopts a new structure type (Pearson code hP162, Wyckoff sequence l(2)k(3)j(2)i(2)hg(2)ecb). In the structure, the Pt and Al atoms form a complex polyanionic [Pt22Al53](delta-) network, while the Ba cations reside in cavities. The structure can be described as a packing of layers, formed by the Pt@Al-n polyhedra parallel to (001). The layers are stacked in an ABCB fashion. Within the [Pt22Al53] framework, one of the shortest Pt-Al distances (239 pm) reported is found, suggesting extremely strong covalent bonding interactions. Due to slightly enhanced displacement parameters of the Al9 site, temperature dependent single-crystal X-ray diffraction (285 and 90 K) and low-temperature heat capacity experiments were conducted. However, no structural phase transition was observed down to 2 K. With the help of DFT calculations, the bonding situation was elucidated in detail, verifying the strong heteroatomic bonding and the destabilization of the structure upon in silico distortions. Mulliken charge calculations confirm the picture of the polyanionic framework and cationic Ba atoms within the cavities.