Anion photoelectron spectroscopy of the linear CnH2n+1O− (n = 1–9) alkoxides

Sarah T. Stokes,John E. Bartmess,Angela Buonaugurio,Yi Wang,Soren N. Eustis,Kit H. Bowen

Chemical Physics Letters（2019）

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摘要

•Photoelectron spectra (PES) were taken of the linear CnH2n+1O− (n = 1–9) alkoxides.•Electron affinities (EAs) and vertical detachment energies (VDEs) were determined.•EA and VDE values increased monotonically with carbon chain length.•OH bond dissociation energies (BDEs) of the corresponding alcohols can be found.•OH BDEs were found using our EAs, gas phase acidities, and a thermochemical cycle.

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关键词

Negative ions,Anion photoelectron spectroscopy,Alkoxides,Bond dissociation energies,Gas phase acidities

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Anion photoelectron spectroscopy of the linear CnH2n+1O− (n = 1–9) alkoxides

Anion photoelectron spectroscopy of the linear CnH2n+1O− (n = 1–9) alkoxides