Texture and Interface Characterization of Iridium Thin Films Grown on MgO Substrates with Different Orientations

Iridium thin films are grown by direct-current plasma magnetron sputtering, on MgO single-crystal substrates with various surface orientations, i.e. (100), (111), and (110). The surface morphology, the crystalline properties of the films, and the substrate–thin-film interface are investigated by atomic force microscopy, X-ray diffraction (XRD), focused ion beam scanning electron microscopy, and high-resolution transmission electron microscopy, respectively. The results reveal that hetero-epitaxial thin films with different crystallographic orientation and notable atomic scale smooth surface are obtained. From the XRD analysis, the following epitaxial relations are obtained: (1) (100) Ir ||(100) MgO out-of-plane and [001] Ir ||[001] MgO in-plane for Ir grown on MgO(100), (2) (110) Ir ||(110) MgO out-of-plane and [1-10] Ir ||[1-10] MgO in-plane for Ir grown on MgO(110), and (3) (111) Ir ||(111) MgO out-of-plane and two variants for in-plane orientation [1-10] Ir ||[1-10] MgO and [1-10] Ir ||[10-1] MgO , respectively, for Ir grown on MgO(111). Because of the large misfit strain (9.7%), the thin films are found to grow in a strain-relaxed state with the formation of geometrical misfit dislocations with a ~ 2.8-nm spacing, whereas thermal strain is stored upon cooling down from the growth temperature (600 °C). The best structural characteristics are obtained for the (111)-oriented films with a mosaicity of 0.3° and vanishingly small lattice distortions. The (100)- and (110)-oriented films exhibit mosaicities of ~ 1.2° and lattice distortions of ~ 1% which can be explained by the larger surface energy of these planes as compared to (111).