Synthesis and molecular characterization of chitosan/starch blends based polyurethanes.

Starch/chitosan modified polyurethanes (PUs) were synthesized by step growth polymerization reaction between −NCO terminated prepolymer and chain extenders (1,4-Butanediol/starch/chitosan). Isophorone diisocyanate (IPDI) was reacted with hydroxyl-terminated polybutadiene (HTPB) to synthesize prepolymer and was further reacted with different moles ratio of starch/chitosan to produced five samples of polyurethane (PU). These samples were characterized by Fourier transformed infrared (FTIR) and Proton nuclear magnetic resonance (1H NMR) spectroscopy. The surface characterizations of PUs were done by scanning electron microscope (SEM). Thermogravimetric analysis showed that the thermal stability of PUs was higher when the mixture of both natural materials was used at equal amounts. It is concluded that combination of both starch and chitosan are efficient for the synthesis of PUs.