Experimental and Theoretical Study of the Vibrationally Excited Reaction Cl + D2 (v = 1, J = 0) → DCl + D.

Vibrationally excited reaction of Cl + D2 (v = 1, j = 0) → DCl + D was investigated by a high-resolution crossed beam experiment, with D2 molecules in the vibrationally excited state prepared by the scheme of stimulated Raman pumping. Differential cross sections (DCSs) were obtained at three collision energies of 4.03, 4.93, and 5.68 kcal/mol. Backward scattering is dominant for both DCl (v' = 0) and DCl (v' = 1) products, and no forward scattering signal was observed at these three collision energies. Collision-energy-dependent DCS in the backward scattering direction was measured at collision energies between 3.62 and 5.97 kcal/mol. Comparing with the DCSs from the vibrational ground state, it is found that the vibrational excitation of D2 molecules significantly enhances the reactivity because of the later barrier nature of the reaction. No obvious oscillatory structure was found in the collision-energy-dependent DCS in the backward scattering direction, suggesting that the title reaction proceeds via a direct abstraction mechanism.