Rubber Magnetic Composites Cross-Linked with Peroxide Curing Systems
Polymer Science, Series B(2020)
摘要
Styrene–butadiene rubber and acrylonitrile–butadiene rubber as elastomer matrices were filled with barium ferrite in order to prepare rubber magnetic composites. For cross-linking of rubber compounds, peroxide curing systems consisting of dicumyl peroxide as curing agent and four types of low molecular weight organic compounds as co-agents were used. The work was focused on the investigation of different types of co-agents on the cross-linking, physical-mechanical and magnetic properties of the prepared composites. The results revealed that the type and amount of co-agent has no influence on magnetic characteristics of composites. On the other hand, cross-link density and physical-mechanical properties were significantly dependent on the composition of curing system. Co-agents contribute to the improvement of adhesion on the interphase filler-rubber. Considering the type of rubber matrix, higher values of tensile strength exhibited composites based on acrylonitrile–butadiene rubber. As magnetic filler and co-agents are polar materials, their compatibility with polar elastomers like acrylonitrile-butadiene rubber is much higher when compared to no-polar elastomers like styrene–butadiene rubber.
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