Fabrication of New Internal Tin Nb$_{3}$Sn Wire Using Sn-Zn Alloy as Sn Core

IEEE Transactions on Applied Superconductivity(2020)

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摘要
We proposed a new configuration for the precursor of Zn-added internal tin (IT) Nb 3 Sn wires, where Zn is added to Sn core and Ti is doped to Cu matrix. The aim is to avoid a Sn-Ti compound layer forming at the Nb filament pack, when one dopes Ti to Sn cores, while maintaining Zn effects such as promotion of Nb 3Sn layer formation: Sn-Ti compound layer could be often a factor to yield inhomogeneous Sn and Ti distribution in the Nb filament modules. We here studied the microstructure and the Jc characteristic of IT wires fabricated using Sn-Zn/CuTi/Nb composite. Use of Sn-Zn core is also effective to increase the hardness of Sn cores about 2 times higher than that of pure Sn core. In Sn-Zn/Cu-Ti/Nb composite samples, the Sn-Ti compound layer was found to be significantly suppressed, compared with Sn-Ti/Cu-Zn/Nb composite samples, which resulted in better Sn andTi distributions. Zn diffusion rate across theCu matrix appears to be so fast that Zn can almost diffuse to the other barrier by the heat treatment at 550 degrees C. Therefore, it is expected to gain the similar effect of Zn addition even for the wires that are made using the Sn-Zn/Cu-Ti/Nb composite, to the Sn-Ti/Cu-Zn/Nb composite wires.
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关键词
Cu-Ti, diffusion reaction, internal-tin, Nb3Sn, Sn-Zn
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