Thermal desorption kinetics of H2O and H2 from rapidly solidified Al-Zn-Mg alloy powders
Thermochimica Acta(2020)
摘要
•Thermal desorption of H2O and H2 from Al-Zn-Mg powder was studied by TPD-MS.•The kinetic parameters of the surface hydroxide film decomposition were determined.•The obtained activation energy (137 kJ/mol) is comparable to those of Al(OH)3 phases.•H2 desorption involves mechanically-induced and diffusion-limited processes.•An experimental evidence for the break-up of the surface oxide film is provided.
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关键词
Aluminum alloy powders,Degassing,Surface hydroxide,Al(OH)3,TPD-MS.
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