Revisiting the Addition of In‐situ Nucleophiles to Allenic Ketones: an Entry Towards Synthesis of Benzodioxins
European journal of organic chemistry(2020)
摘要
The manuscript delineates a revisit towards regioselective addition of in situ generated negative nucleophiles to allenic ketones in the presence of a base. A wide variety of allenic ketones as well as nucleophiles are viable in this transformation. A direct ring annulation towards the challenging benzodioxin skeleton synthesis has been developed. Environmentally benign protocol and wide substrate scope are the notable features of this methodology.
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关键词
Regioselective,In situ nucleophiles,beta-Vinyl,Benzodioxins
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