Iron-Promoted Catalytic Activity of Selenium Endowing the Aerobic Oxidative Cracking Reaction of Alkenes.
Organic letters(2023)
Abstract
Oxidative cracking of alkenes is a significant process in industry. In this work, it was found that catalyzed by Se/Fe via hybrid mechanisms, the carbon-carbon double bond in alkenes can break to produce carbonyls under mild conditions. Since O can be used as a partial oxidant, the employed HO amount can be reduced (90 mol % vs 250 mol %) to avoid the peroxide residues, making the process even safer for operation.
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Key words
aerobic oxidative cracking reaction,selenium,catalytic activity,iron-promoted
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