Bismuth activated succulent-like binary metal sulfide heterostructure as a binder-free electrocatalyst for enhanced oxygen evolution reaction.
Journal of Colloid and Interface Science(2020)
摘要
Oxygen evolution reaction (OER) is the key to achieve highly efficient hydrogen production during water splitting. Herein, flexible nanorods-integrated succulent-like Bi2S3/Ni3S2/NF heterostructure has been prepared by a facile solvothermal method and applied for OER. We highlight the unique nonequivalent sp3 hybridization of P-region metal based sulfides, which makes a possibility of electronic inductive effect and enhanced electrocatalytic performance. The Bi2S3/Ni3S2/NF catalyst shows low overpotential 268 mV at 10 mA cm−2 and low Tafel slope of 82 mV dec−1. Long-term stability evaluated at high current density suggests that succulent-like Bi2S3/Ni3S2 could be a promising alternative to noble-metal based electrocatalysts for water oxidation reaction in alkaline medium.
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关键词
Oxygen evolution reaction,Bi2S3/Ni3S2/NF,Electronic inductive effect,Self-assembled,Heterostructure
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