Ferriporphyrin-inspired MOFs as an artificial metalloenzyme for highly sensitive detection of H2O2 and glucose

In this work, inspired by the active sites of ferriporphyrin-based metalloenzymes, Fe-MOFs by using ferric as the metal center and a porphyrin analog as the organic ligand were developed as an artificial metalloenzyme, offering an efficient strategy for the development of highly stable and efficient metalloenzymes, showing great potential in catalysis, energy transfer, biosensing and medical diagnosis.