Manganese tetraphenylporphyrin bromide and iodide. Studies of structures and magnetic properties

Alexandria N. Bone,Shelby E. Stavretis,J. Krzystek,Zhiming Liu,Qiang Chen,Zheng Gai,Xiaoping Wang,Carlos A. Steren,Xian B. Powers,Andrey A. Podlesnyak,Xue-Tai Chen,Joshua Telser,Haidong Zhou,Zi-Ling Xue

Polyhedron（2020）

引用 7|浏览25

暂无评分

摘要

Mn–Br/I bonds in Mn(TPP)X are surprisingly longer than Fe–Br/I bonds in Fe(TPP)X (X = Br, I), although Mn(III) and Fe(III) ions have the same radii. Mn(TPP)Br has easy-axis anisotropy (D < 0), while Mn(TPP)I is easy-plane (D > 0). Magnitude of the axial anisotropy decreases from Mn(TPP)Cl to Mn(TPP)Br.

查看译文

关键词

Mn porphyrin complexes,zero-field splitting (ZFS),HFEPR,inelastic neutron scattering (INS),Hirshfeld surface analysis

AI 理解论文

溯源树

样例

生成溯源树，研究论文发展脉络

Chat Paper

正在生成论文摘要