Unprecedented activity and stability on zirconium phosphates grafted mesoporous silicas for renewable aromatics production from furans

Journal of Catalysis(2020)

引用 23|浏览11
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摘要
•In-situ ZrP species formed on the silanol groups of silica by chemical grafting method.•Higher activity on ZrP grafted SBA-15 was observed for selective para-xylene production.•Surface ZrP species and optimal amount of acid sites were crucial for aromatics production.•Tunable surface properties against coke deposition of ZrP grafted SBA-15 were characterized.
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关键词
Aromatics,Biomass,Optimal Brönsted/Lewis acid sites,Ordered mesoporous silicas,Zirconium phosphate species
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