Ternary nickel(II) complexes with histidine and glycylglycine in solution: Thermodynamic approach

Inorganica Chimica Acta(2020)

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摘要
•The ionic composition of solutions in the nickel-histidine-glycylglycine system has been refined.•Mixed complexes of the types NiGGmHnHism (m = 1, 2; n = 0, 1,-1) have been revealed.•The thermodynamic parameters of glycylglycine addition to Ni(II) histidine complex are analyzed.•Coordination modes of amino acid and dipeptide residues have been proposed based on a thermodynamic approach.
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关键词
Mixed-ligand complex formation,Calorimetry,Nickel,Glycylglycine,Histidine
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