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Enhancement of Clathrate Hydrate Formation Kinetics Using Carbon-Based Material Promotion.

FRONTIERS IN CHEMISTRY(2020)

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摘要
Although hydrate-based technology has been considered as a safe and environmentally friendly approach for gas storage and transportation in recent decades, there are still inherent problems during hydrate production, such as a long induction time, slow formation kinetics, and limited hydrate storage capacity. Attempts to resolve these issues have resulted in the development of various kinetics promoters, among which carbon-based materials have become one of the most attractive owing to their unique promotion effect. Herein, results on promotion by bulk wetted carbon materials in the forms of a packed bed, carbon particles in a suspension, and nano-carbon materials in a nanofluid are collected from the published literature. Meanwhile, the promotion mechanisms and influencing factors of the carbon-based promoters are discussed. The purpose of this mini-review is to summarize recent advances and highlight the prospects and future challenges for the use of carbon-based materials in hydrate production.
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关键词
gas hydrates,methane storage,efficient promoter,carbon-based materials,kinetic promotion
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