Incorporation of Coinage Metal-Nhc Complexes into Heptaphosphide Clusters.

Minyoung Jo,Jingbai Li,Alina Dragulescu-Andrasi,Andrey Yu Rogachev,Michael Shatruk

Dalton Transactions（2020）

引用 3|浏览36

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摘要

Cu(i) and Au(i) ions, capped with an N-heterocyclic carbene (NHC), react with (TMS)3P7 (TMS = trimethyl-silyl) to afford an η4-coordinated anion [NHCDippCu-P7(TMS)]- and a neutral trinuclear complex (NHCDippAu)3P7. Protecting the P7 cage with the TMS groups is instrumental in controlling the course of these reactions.

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关键词

Transition Metal Catalysis,Metal Complexes,Cross-Coupling Reactions

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