Diffusion measurements with continuous hydrogenation in PHIP

Journal of Magnetic Resonance(2020)

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摘要
•Diffusion experiments in highly diluted samples with sensitivity boost are shown.•Main drawbacks with the technique are addressed by means of PHIP.•Reactions with continuous flow are performed in a setup based on Teflon tubes.•Very stable parahydrogen reactions allow reliable 2D experiments.
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关键词
DOSY,PHIP,Diffusion,Hyperpolarization,PSGE,Double PSGE,NMR,J-coupling,Spin dynamics
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