Unfolding Multi-Stranded Perylene Bisimide Lc Columns - A Mesogen Design For Efficient Nanoscale Multilayer Self-Assembly

A mesogen tethered, twofold bay-substituted perylene bisimide (PBI) is found to generate a columnar phase, which unfolds and gradually transforms to a completely nanosegregated multilayer columnar-lamellar liquid crystal. The structure is based on the formation of bundles of H-bonded PBI strands in the central layer. This design opens the way to new complex multifunctional materials.