A new sandwich polyoxometalate based on Keggin-type monolacunary polyoxotungstoborate anion, [Zr(α-BW11O39)2]14−

Yujuan Niu,Bin Liu,Ganglin Xue,Huaiming Hu,Feng Fu,Jiwu Wang

Inorganic Chemistry Communications（2009）

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摘要

A new sandwich-type polyoxometalate based on Keggin-type monolacunary anion, [Zr(α-BW11O39)2]14− was synthesized and characterized by IR spectroscopy, UV electronic spectroscopy, cyclic voltammetry and single-crystal X-ray diffraction. This is the first report of crystal structure for the sandwich Keggin-type polyoxotungstoborate.

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关键词

Polyoxometalate,Boron,Zirconium,Sandwich-type

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