Cu2O Nanoparticles for the Degradation of Methyl Parathion.
Beilstein Journal of Nanotechnology(2020)
摘要
Methyl parathion (MP) is one of the most neurotoxic pesticides. An inexpensive and reliable one-step degradation method of MP was achieved through an aqueous suspension of copper(I) oxide nanoparticles (NPs). Three different NPs sizes (16, 29 and 45 nm), determined with X-ray diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM), were synthesized using a modified Benedict's reagent. 1H nuclear magnetic resonance (NMR) results show that the hydrolytic degradation of MP leads to the formation of 4-nitrophenol (4-NPh) as the main product. While the P=S bond of MP becomes P=O, confirmed by 31P NMR. Although Cu2O is a widely known photocatalyst, the degradation of methyl parathion was associated to the surface basicity of Cu2O NPs. Indirect evidence for the basicity of Cu2O NPs was achieved through UV-vis absorption of 4-NPh. Likewise, it was shown that the surface basicity increases with decreasing nanoparticle size. The presence of CuCO3 on the surface of Cu2O, identified using X-ray photoelectron spectroscopy (XPS), passivates its surface and consequently diminishes the degradation of MP.
更多查看译文
关键词
copper(I) oxide (Cu2O),Cu2O nanoparticles,degradation,methyl parathion,surface basicity
AI 理解论文
溯源树
样例
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要