Morphology engineering of cobalt embedded in nitrogen doped porous carbon as bifunctional oxygen electrocatalyst for Zn-air battery
Materials Today Energy(2020)
摘要
The structure and morphology of catalysts can affect their catalytic performance due to the various exposed active sites and mass transport pathway. Herein, we synthesis a serious of Co-based complex with spindle-like, branched spindle, disk-like and quasi-sphere morphologies and found that the crystal growth is controlled by multistep crystal splitting mechanism. We further transferred the Co-based complex into Co embedded in nitrogen doped porous carbon (Co@NC) by thermal annealing to investigate the morphology effect of electrocatalysts. It was found the catalytic performance of the catalysts exhibits a trend of quasi-sphere (Co@NC-80) > spindle-like (Co@NC-300) > branched spindle (Co@NC-200) > disk-like (Co@NC-130), probably due to the various exposed efficient active sites of the catalyst induced by their morphology, and various mass transport resistance in the catalysts. Impressively, the Co@NC-80 exhibits comparable ORR (oxygen reduction reaction) activity with Pt/C and better OER (oxygen evolution reaction) activity than RuO2, highlighting its bifunctional catalytic performance for metal-air batteries. The Zn-air catalyzed by Co@NC-80 exhibits an open circuit voltage of 1.35 V, a high specific capacity of 887.5 mA h/g and a max power density of 168.7 mW cm−2, as well as excellent long-time stability with no obvious performance decay after charge-discharge cycling of 140 h.
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关键词
Bifunctional catalyst,Oxygen evolution reaction,Oxygen reduction reaction,Metal complex,Morphology effect
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