Synthesis, Crystal Structure and Catalytic Activity Palladium(II) Complexes Containing Bulky Azole Ligands

Zhang Meng-Yao,Zhang Ying-Ying,Zhang Hui-Xin, Wang Shen, Wang Ya-Qi,Zeng Yong-Fei,Liu Gui-Yan

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY（2020）

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摘要

Bulky azole ligands in combination with PdCl2 provide three new palladium(II) complexes. All these complexes, as pre-catalysts, have high catalytic efficiency for the Suzuki-Miyaura cross-coupling reactions of sterically hindered aryl chlorides and good to high yields are obtained with low catalysts loadings (0.1 mol%) under mild conditions in air.

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关键词

palladium(II) complexes,crystal structure,catalytic activity,Suzuki-Miyaura cross-coupling

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