High sensitivity fluorescence up-conversion spectroscopy of (MLCT)-M-3 emission of metal-organic complexes

Li Liu,Damianos Agathangelou,Thomas Roland,Olivier Cregut, Thibaud Duchanois,Marc Beley,Jeremie Leonard,Philippe Gros,Stefan Haacke

EPJ Web of Conferences（2019）

引用 4|浏览2

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摘要

We demonstrate the implementation of a broadband fluorescence up-conversion set-up with high signal-to-noise ratio and dynamic range allowing for the detection of weak luminescence from triplet states in Fe(II) NHC complexes. Based on the experimentally determined radiative rates and the emission spectra, these states have dominant MLCT character.

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