Th-230 Normalization: New Insights on an Essential Tool for Quantifying Sedimentary Fluxes in the Modern and Quaternary Ocean

Th-230 normalization is a valuable paleoceanographic tool for reconstructing high-resolution sediment fluxes during the late Pleistocene (last similar to 500,000 years). As its application has expanded to ever more diverse marine environments, the nuances of Th-230 systematics, with regard to particle type, particle size, lateral advective/diffusive redistribution, and other processes, have emerged. We synthesized over 1000 sedimentary records of Th-230 from across the global ocean at two time slices, the late Holocene (0-5,000 years ago, or 0-5 ka) and the Last Glacial Maximum (18.5-23.5 ka), and investigated the spatial structure of Th-230-normalized mass fluxes. On a global scale, sedimentary mass fluxes were significantly higher during the Last Glacial Maximum (1.79-2.17 g/cm(2)kyr, 95% confidence) relative to the Holocene (1.48-1.68 g/cm(2)kyr, 95% confidence). We then examined the potential confounding influences of boundary scavenging, nepheloid layers, hydrothermal scavenging, size-dependent sediment fractionation, and carbonate dissolution on the efficacy of Th-230 as a constant flux proxy. Anomalous Th-230 behavior is sometimes observed proximal to hydrothermal ridges and in continental margins where high particle fluxes and steep continental slopes can lead to the combined effects of boundary scavenging and nepheloid interference. Notwithstanding these limitations, we found that Th-230 normalization is a robust tool for determining sediment mass accumulation rates in the majority of pelagic marine settings (>1,000 m water depth).