The Application on Nitrogen-Coordinating Transition Metal Complexes on Hydrosilylation

The study of nitrogen-coordinating transition metal complexes has been a significant development in the recent decades. Designing different excellent nitrogen ligands coordinated with various transition metal complexes, which it's of great value in hydrosilylation reaction. In this paper, the latest progress of the application in nitrogen-coordinating transition metal (Rh, Fe, Re, Co, Zn and so on) complexes to ketone hydrosilylation or alkene hydrosilylation is reviewed. The design of optimized bisoxazolines or dihydropyrrolo nitrogen-containing ligands will greatly facilitate the successful development of nitrogen-containing iron, rhenium, cobalt complexes in the hydrosilylation of ketone or imine.