Synthesis, structures, and electrochemical and optical properties of lambda(5)-phosphinine derivatives functionalized tetrathiafulvalene analogs

Aya Yoshimura,Hitoshi Kimura,Ayaka Handa,Naoki Hashimoto, Makoto Yano,Shigeki Mori,Takashi Shirahata,Minoru Hayashi,Yohji Misaki

Tetrahedron Letters（2020）

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摘要

•λ5-Phosphinine derivatives functionalized TTF analogs were synthesized.•These molecules exhibited three-pairs of one-electron redox waves.•The fluorescence of them is quenched by intramolecular electron transfer.

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关键词

λ5-Phosphinine derivatives,Tetrathiafulvalene analogs,Electrochemical properties,Optical properties,External stimulus response fluorophores

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