Coupling between clay swelling/collapse and cationic partition
Geochimica et Cosmochimica Acta(2020)
摘要
•Na+/K+ partition through clay responses to aqueous activity condition.•K+ ions are enriched in montmorillanite under all studied circumstances.•A low water activity strengthens K+ ion enrichment in montmorillanite.•Clay swelling/collapse is quantitatively coupled to cationic partition.
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关键词
Montmorillonite,Na+,K+,Partition,Water,Thermodynamics
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