A New Pre-Sodiation Additive For Sodium-Ion Batteries

ENERGY STORAGE MATERIALS(2020)

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摘要
We demonstrate the potential of diethylenetriamine penta-acetic acid salt (DTPA-5Na) as a sacrificing sodium supply source for blending with sodium-deficient tunnel-type Na0.44MnO2. Herein, we report that DTPA-5Na shows presodiation effects on the sodium-deficient cathode. With the addition of DTPA-5Na to the Na0.44MnO2 (polyvinylidene-fluoride-less) electrode, the charge capacity increased from similar to 58 to similar to 128 mAh g(-1). Thus, the DTPA-5Na provides additional capacity (similar to 70 mAh g(-1)), originating from the five sodium ions in the DTPA-5Na structure during oxidative reaction. Furthermore, DTPA-5Na/Na0.44MnO2//0.5 M NaPF 6 in a PC:FEC (98:2 v/v.%)//hard carbon full cell exhibits a high coulombic efficiency close to 100% with long-term cycling performance. Interestingly, the increase in discharge capacity is shown to be associated with the electro-conducting nature of the C3N deposits formed on the surface of Na0.44MnO2. Our findings indicate that the introduction of DTPA-5Na as a sacrificing additive in a cathode material may provide a new opportunity to apply sodiumdeficient cathode materials in practical sodium-ion batteries.
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关键词
DTPA-5Na, Additive, Cathode, Sodium, Battery
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