Redistribution reaction on a six-fold coordinated Sn(IV) atom and reactions towards axially unsymmetric substituted Sn(IV) porphyrins

Stefan Stadlbauer, Doris Grössl,Roland Fischer,Nicola Demitri,Frank Uhlig

Journal of Organometallic Chemistry（2020）

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摘要

•Redistribution reaction on a six fold coordinated Sn(IV)atom display an equilibrium.•The equilibrated reaction is thermally activated.•Accessing axially unsymmetrical substituted porphyrins via bypassing the equilibrium.•Three single crystal XRD structures of unsymmetrical substituted Sn(IV)porphyrins.•NMR studies on scrambling reactions on higher coordinated Sn(IV) atoms.

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关键词

Kocheshkov,Redistribution reaction,Axially asymmetric substituted Sn(IV) porphyrin

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