Thermal Behavior and Failure Mechanism of Large Format Lithium-Ion Battery
Journal of solid state electrochemistry(2020)
摘要
Thermal runaway (TR) behavior of 38 Ah lithium-ion batteries with various states of charge (SOC) is experimentally investigated in this work using extended volume plus accelerating rate calorimeter (EV+ ARC). Some of the critical kinetic parameters, such as onset exothermic temperature ( T onset ), temperature of TR ( T TR ), and maximum temperature ( T max ), can be obtained to characterize the risks of TR event. The impact of SOC on thermal stability of the battery is researched. It is found that the higher the SOC state, the lower the battery safety. Thermal features of both the cathode and anode, as well as the materials, are also investigated. The morphology and the structure change of the materials are characterized by scanning electron microscope (SEM) and X-ray diffraction (XRD). Finally, a general theory is proposed and detailed reactions are summarized in this work. The thermal runaway follows a mechanism of chain reactions, during which the decomposition reactions of the battery component materials occur one after another.
更多查看译文
关键词
Lithium-ion battery,Thermal runaway,Accelerating rate calorimeter,Mechanism
AI 理解论文
溯源树
样例
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要